How Can I Burn Vanishing Point (PAL) without using CloneCD????

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CDRWin was originally written for the express purpose of copying PSX games.
When you install the program it is installed with the default options set correctly for that purpose.
You need change nothing, except to make sure that raw is ticked, if it is not then your reader/burner may not be capable of correctly producing the .bin file.
You can only try, if it doesn't work it may mean that your hardware cannot do it.