PSX backups and Creative CD-RW 4224E

First, sorry for bad english...
I have a CD-RW model 4224E (Creative Labs), and try to make PSX backups with that. To make this, I used CloneCD, CDRWin, PSXCopy 2000, and the copies don't work in the PSX console (PS One, with Mod-chip). I make, for example, a image file of TEKKEN 3 and Castlevania and execute the games using the emulator VGS+Daemon, and them working perfectly!!! But, the backup cd's don´t work... :-( I make copies using CD-CD (on the fly), and Image-CD, but I lose my time... nothing work. My CD-RW don´t support the PSX disk format? Is that? And now, what I have to do???