I have a CD-RW, now what?

[Neandrake]

I'm quite familiar with burning cds using Nero and CloneCD (for those tough games). However, someone asked me to see if I could get him Madden 2003 for his PlayStation 2. I was wondering if it is possible to burn the game to a CD, and how. Thanks for any info, I'm more familiar with copying games and image files and such.