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The Philips CDRW2412 is not the right reader/burner for PS2 games and is thus not fully CloneCD compatible. Likewise Fireburner is unable to use DAO.
I don't know whether or not WE6 is a CD game or a DVD game. If it is a CD game, it will be 640MB or less. If it is a DVD game, then you have a rip onto CD and it can be in any condition, good or bad - high probability that the rip itself is bad.
Neo2.2 will play rips > 640MB and less than 700MB and the PS2, once chipped properly, will play both NTSC and PAL games.
My memory is failing me on this subject, but it may be that, seeing as your PS2 is a v4, you need AR2/v1.9 (you didn't say which version you) had
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[b][color=red]Charlie[/b][/color]
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