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I think you alread have it the right way my friend: DVD=master, CDRW=slave.
Have you tried the following:
1. Defragment your hard-drive
2. Optimise your Hard-disk cache
3. Create a disc image before burning
4. Disable any programs that run in the background when Win starts!
5. Keep other program usage as low as possible, when burning
6. Lower record speed
Let us know how ya got on. All the best,
Wayne
Hope this helps
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