[DarkLeftos]

Here you go then:

You didn't need to buy Alcohol, you could use Daemon Tools which is free, and in terms of mounting is much better than Alcohol. Anyway...
1. Download the mini-image from any site you want (obviously I should suggest gamecopyworld.com) and save it to a folder you'll remember (that should answer your BTW2)
2. Start Alcohol 120%, and on the bottom of the program's window, under Virtual CD/DVD-ROM, there should be (by default) one device. Right-click on it, and select Mount Image. Browse through the window that popped-up to the mini-image and double click on it.
3. After some seconds, the image should be fully mounted. Start the game from the shortcut, closing any My Computer windows that popped-up.

(I'll use By The Way instead of P.S. since you used it too...)

BTW1: Here's the link to download FIFA 06's mini-image: http://d06.gamecopyworld.com/?d=2005&f=FIFA06_MI!rar
BTW2: If you think browsing through gamecopyworld.com is too hard... er... I won't suggest taking Internet lessons, I'll just be nice and tell you how to make an image from your original FIFA CD/DVD.

1. Start Alcohol 120% and click on the Image Making Wizard.
2. Click Next, and select where you want the image to be saved.
3. Click Next and wait for the program to finish reading the disc.
4. Follow steps 2-3 from the mini-image guidelines above, although now make sure you browse and select your full image.