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In regards to Chronicles of Rid****, it uses (i think) a compression technique called Extended Compression Architecture - hence the use of files containing the extension *.xca. I think that there's a program called Data Accelerator Compression that can read these *.xca files and possibly - in theory - extract and recompress the files so as to make it possible to fit onto DVD.
But until then it looks like the only way is to create the discs into an ISO format and burn those files to a DVD.
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