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Usually two methods of making a backup of a backup:
1) Creating an ISO image using something like CDRWIN or DiscJuggler, both will create images, just DJ will create CDI images instead. Once the image is made, load the image and burn it to CD.
2) Do a straight CD-to-CD copy, have the backup in your CD-ROM drive and the blank CD-R in the CD-R(W) drive and burn it.
If both of these methods are failing, then it is most likely human error, to which I cannot assist you.
~The Masked M0M0~
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