Alcohol 120% can copy most games EXCEPT the ones using the latest protections (StarForce v3, SafeDisc v3, SecuROM v5, TAGES), but it also depends on your CD/DVD-Burner if it is able to do so
Alcohol 120% is currently the best @ copying games. A free demo is available to test it our!
Have a look here:
http://spacetarget.com/games/gcw_cd-backup.shtml