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Sounds like a problem with the ownership of the files. To solve this, go to the configuration panel and start Folder Options. On the second tab, you should find a setting called "use simple file sharing", switch that one to off. Now when you get the Properties of the old Documents And Settings folder, you get an extra Security tab where you can add an Owner for that folder and any subfolders of the folder. Add the name under which you logged in, and you should be able to access all files now. You can then switch "Use Simple File Sharing" on again.
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