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What DVD Drive/Writer have you got and have you checked the supported drive list on PowerDVD website?
You should also consider using the following:-
1. DVD Decrypter - takes about 20mins.
2. DVD2one - takes 15-20 mins and puts any movie on one DVDR.
3. Burn with the latest version of Nero - about 30mins.
As I said any movie will fit on one DVDR without any noticeable loss of quality and it only takes about an hour.
I used to use DVDXCopy but now I use DVD2one, it's brilliant.
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