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Audio CD: Select Audio CD compilation in Nero, then drag those mp3 to the compilation window, Nero will make/burn an Audio CD that you can play in any CD / DVD Player.
Video CD: I guess your CD Writer is a CD Writer not a DVD Writer, so you only can use Nero to make VCD or SVCD. Select Video CD or Super VCD compilation in Nero, then drag those mpeg to the compilation window, Nero will prompt you to re-encode imcompatible files, then it will make/burn an correct CD for you.
For better re-encoding result, I would recommend TMPGenc. And both TMPGenc and Nero need additional $$ to re-encode SVCD standard, but not VCD, or should I call MPEG1, VCD encoding is free in TMPGenc, but this kind of re-encoding need times, very slow...
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